Pyridines and pyridinium salts from cyanoacetamides

descriptionPublicationkeyboard_double_arrow_right Article 01 May 1976 English Publisher:CSIRO PublishingJournal:Australian Journal of Chemistry, volume 29, pages 1,039-1,050 (issn: 0004-9425, eissn: 1445-0038,

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Authors: AL Cossey; RLN Harris; JL Huppatz; JN Phillips;

doi: 10.1071/ch9761039

Pyridines and pyridinium salts from cyanoacetamides

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Abstract

Self-condensation of cyanoacetamides under the influence of phosphorus oxychloride leads to pyridines and pyridinium salts in high yield. The mechanism of the reaction is discussed and evidence for the structure of the products is described. The chemical activity of the new pyridine derivatives has been briefly explored.

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