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Australian Journal of Chemistry

Article . 1973 . Peer-reviewed

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Australian Journal of Chemistry

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Nitrones and oxaziridines. VII. Cycloaddition reactions of nitrones with carbon disulphide

descriptionPublicationkeyboard_double_arrow_right Article 01 Jan 1973 English Publisher:CSIRO PublishingJournal:Australian Journal of Chemistry, volume 26, page 2,177 (issn: 0004-9425,

Authors: Dsc Black; Keith G. Watson;

doi: 10.1071/ch9732177

Nitrones and oxaziridines. VII. Cycloaddition reactions of nitrones with carbon disulphide

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Abstract

The cyclic aldo nitrones (3)-(5) undergo cycloaddition reactions with carbon disulphide to yield the related thiolactams (6)-(8), presumably via intermediate 1,4,2-oxathiazolidine-5-thiones, which could not be isolated or detected. N-(Benzylidene)-methylamine N-oxide undergoes a similar conversion into the related thioamide, but the reaction is not shown by all nitrones.

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