Cobalt(II) gluconate complexes

descriptionPublicationkeyboard_double_arrow_right Article 01 Jul 1970 English Publisher:CSIRO PublishingJournal:Australian Journal of Chemistry, volume 23, pages 1,367-1,373 (issn: 0004-9425, eissn: 1445-0038,

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Authors: JF Ashton; WF Pickering;

doi: 10.1071/ch9701367

Cobalt(II) gluconate complexes

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Abstract

A study of the cobalt(11) gluconate system has confirmed the existence of an unstable cationic species [Co(C6H1107)]+, in solutions of pH <7.5, and two insoluble compounds, CO2(OH)3(C6H11O7),xH2O and CO3(C6H10O7)2(OH)2,2H2O, formed in solutions of pH 7.5-9.5. Above pH 9.5 an anionic species, which is subject to rapid auto-oxidation, exists in solution.

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