Vacuum freeze-drying (VFD) technology has gained extensive application across various sectors, particularly in environmental applications, where it is primarily utilized for the fabrication of environmental functional materials and the conservation of environmental organisms. This technology is applicable to soil enhancement, the remediation of aquatic pollutants, energy storage in thermoelectric materials, and the preservation of bacterial cultures. This review synthesizes the most recent advancements in VFD technology within the environmental domain, elaborating on its technical fundamentals, operational procedures, practical applications, and distinctive benefits. Furthermore, the article explores the prospective development trajectory and potential challenges for this technology in the environmental sector, offering scientific guidance for its continued application and insights into its innovative progression.