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The Journal of Chemical Physics
Article . 2022 . Peer-reviewed
License: CC BY
Data sources: Crossref
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The Journal of Chemical Physics
Article . 2022
License: CC BY
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Radboud Repository
Article . 2022
Data sources: Radboud Repository
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Single-orientation colloidal crystals from capillary-action-induced shear

Authors: Nicholas H. P. Orr; Taiki Yanagishima; Igor P. Dolbnya; Andrei V. Petukhov; Roel P. A. Dullens;

Single-orientation colloidal crystals from capillary-action-induced shear

Abstract

We study the crystallization of colloidal dispersions under capillary-action-induced shear as the dispersion is drawn into flat walled capillaries. Using confocal microscopy and small angle x-ray scattering, we find that the shear near the capillary walls influences the crystallization to result in large random hexagonal close-packed (RHCP) crystals with long-range orientational order over tens of thousands of colloidal particles. We investigate the crystallization mechanism and find partial crystallization under shear, initiating with hexagonal planes at the capillary walls, where shear is highest, followed by epitaxial crystal growth from these hexagonal layers after the shear is stopped. We then characterize the three-dimensional crystal structure finding that the shear-induced crystallization leads to larger particle separations parallel to the shear and vorticity directions as compared to the equilibrium RHCP structure. Confocal microscopy reveals that competing shear directions, where the capillary walls meet at a corner, create differently oriented hexagonal planes of particles. The single-orientation RHCP colloidal crystals remain stable after formation and are produced without the need of complex shear cell arrangements.

Country
Netherlands
Keywords

Microscopy, Spheres, Flow, Physical Chemistry of Soft Matter, Induced order, Particles, Suspensions, Dispersions, Crystallization, Alignment

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    popularity
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    influence
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    impulse
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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
3
Top 10%
Average
Average
Green
hybrid