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Fock similarity transformation of the electronic Hamiltonian

Authors: Paolo Lazzeretti;

Fock similarity transformation of the electronic Hamiltonian

Abstract

The covariance of the one-electron Schrödinger equation in a gauge transformation of electromagnetic potentials is customarily discussed, introducing the relationships that describe their changes, induced by a generating function of position coordinates and time, together with a phase transformation of the wavefunction, according to a proposal by Fock, i.e.,2 relying on three distinct hypotheses. The present note shows that (i) a single similarity transformation employing the Fock phase factor is sufficient to prove the covariance of the wave equation and (ii) the Fock transformations of the nonperturbed Hamiltonian ĥ(0) and of the time-derivative operator determine the changes appearing in first and second-order Hamiltonians, ĥ(1) and ĥ(2), a single term being obtained by Fock-transforming ĥ(1).

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
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