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The Journal of Chemical Physics
Article . 2019 . Peer-reviewed
Data sources: Crossref
https://dx.doi.org/10.48550/ar...
Article . 2019
License: arXiv Non-Exclusive Distribution
Data sources: Datacite
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Surface van der Waals forces in a nutshell

Authors: Luis G. MacDowell;

Surface van der Waals forces in a nutshell

Abstract

Most often in chemical physics, long range van der Waals surface interactions are approximated by the exact asymptotic result at vanishing distance, the well known additive approximation of London dispersion forces due to Hamaker. However, the description of retardation effects that is known since the time of Casimir is completely neglected for the lack of a tractable expression. Here we show that it is possible to describe surface van der Waals forces at arbitrary distances in one single simple equation. The result captures the long sought crossover from non-retarded (London) to retarded (Casimir) interactions, the effect of polarization in condensed media, and the full suppression of retarded interactions at large distance. This is achieved with similar accuracy and the same material properties that are used to approximate the Hamaker constant in conventional applications. The results show that at ambient temperature, retardation effects significantly change the power law exponent of the conventional Hamaker result for distances of just a few nanometers.

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Keywords

Condensed Matter - Materials Science, Materiales, Condensed Matter - Mesoscale and Nanoscale Physics, 2211.28 Superficies, Materials Science (cond-mat.mtrl-sci), FOS: Physical sciences, 2210 Química Física, Química, 2202 Electromagnetismo, 3312 Tecnología de Materiales, Mesoscale and Nanoscale Physics (cond-mat.mes-hall), 23 Química, Óptica (Física), Electromagnetismo, Química física (Física), Superficies (Física), Química física (Química), 2209.19 Óptica Física

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
22
Top 10%
Top 10%
Top 10%
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