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image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao https://doi.org/10.1...arrow_drop_down
image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
https://doi.org/10.1007/978-3-...
Part of book or chapter of book . 2018 . Peer-reviewed
License: Springer TDM
Data sources: Crossref
The Journal of Chemical Physics
Article . 2015 . Peer-reviewed
Data sources: Crossref
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Nonlinear dielectric response of polar liquids

Authors: Dmitry V. Matyushov;

Nonlinear dielectric response of polar liquids

Abstract

The dielectric constant of a polar liquid in a strong electric field changes, in the lowest order, proportionally to the squared field magnitude. The proportionality coefficient (dielectric slope) is traditionally analyzed by mean-field models in terms of the saturation of alignment of individual dipoles as prescribed by the Langevin function. Only a decrease of the dielectric constant induced by the field is allowed by this model, in contrast to observations. Here, the dielectric slope is expressed in terms of the fourth-order cumulant of the liquid dipole moment. The cumulant is in turn separated into the two-particle dipolar correlations, expressed in terms of the Kirkwood factor and the liquid compressibility, and higher, triple and four-particle, dipolar correlations. The model allows both positive and negative dielectric slopes. Two-particle and higher-order correlations largely compensate each other. The analysis of experimental data suggests that dielectric slope gives experimental access to non-trivial triple and four-particle orientational correlations in polar liquids.

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
32
Top 10%
Top 10%
Top 10%
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