The infrared spectrum of the benzene–Ar cation

descriptionPublicationkeyboard_double_arrow_right Article 22 Dec 1999 United States, Netherlands English Publisher:AIP PublishingJournal:The Journal of Chemical Physics, volume 111, pages 10,750-10,753 (issn: 0021-9606, eissn: 1089-7690,

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Authors: Satink, R.G.; Piest, H.; von Helden, G.J.; Meijer, G.J.M.; Meijer, G.J.M.;

doi: 10.1063/1.480438

handle: https://repository.ubn.ru.nl/handle/2066/98974 , 2066/98974 , 21.11116/0000-000B-65D8-0 , 21.11116/0000-000B-65DA-E , 1811/20439

The infrared spectrum of the benzene–Ar cation

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Abstract

The infrared (IR) absorption spectra of the jet-cooled C6H6 and C6D6 cations, complexed with Ar, are measured throughout the 450–1500 cm−1 region via IR-laser-induced vibrational dissociation spectroscopy. The IR spectrum of the C6H6–Ar cation is dominated by a Fermi resonance between the IR active ν11 mode and two components of the combination mode of the lowest frequency modes ν6 and ν16. A stringent upper limit of 316 cm−1 is found for the value of the dissociation limit D0 of the neutral C6D6–Ar complex.

Countries

United States, Netherlands

Related Organizations

Radboud University Nijmegen
Netherlands
Dutch Research Council
Netherlands
Dutch Institute for Fundamental Energy Research
Netherlands
The Ohio State University
United States

Keywords

Molecular and Biophysics, Experimental Molecular Physics, 540, 530

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