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The Journal of Chemical Physics
Article . 1999 . Peer-reviewed
Data sources: Crossref
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Glassy dynamics in DNA: Ruled by water of hydration?

Authors: Sokolov, A. P.; Grimm, H.; Kahn, R.;

Glassy dynamics in DNA: Ruled by water of hydration?

Abstract

Inelastic neutron scattering spectra of DNA-fibers are analyzed using ideas formulated recently in the field of the glass transition. The analysis reveals two temperatures, namely, T∼180–200 K and T∼230 K, at which the dynamics of DNA exhibits qualitative changes. The former is similar to the glass transition temperature, whereas the latter is similar to the crossover temperature recognized now as an important point for the dynamics of the glass transition. Exactly in this temperature range many other hydrated biopolymers show some dynamic transition and strong slowing down of their functions. The crossover temperature appears to be close to the crossover temperature of bulk water. A possible relation of the dynamic transition to functions of biomolecules and also to the dynamic transition in the hydration shell is discussed.

Country
Germany
Keywords

info:eu-repo/classification/ddc/540

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    selected citations
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    This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    71
    popularity
    This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
    Top 10%
    influence
    This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    Top 10%
    impulse
    This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
71
Top 10%
Top 10%
Top 10%
Green
bronze