Extended superstructure in Tl-rich liquid Cs–Tl alloys

descriptionPublicationkeyboard_double_arrow_right Article 08 Jun 1998 Netherlands English Publisher:AIP PublishingJournal:The Journal of Chemical Physics, volume 108, pages 9,214-9,217 (issn: 0021-9606, eissn: 1089-7690,

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Authors: van der Aart, S. A.; Verkerk, P.; Badyal, Y. S.; van der Lugt, W.;

doi: 10.1063/1.476375

handle: 11370/47ef9bac-fdad-4b4c-a965-73041c1dd071

Extended superstructure in Tl-rich liquid Cs–Tl alloys

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Abstract

The structure factors of liquid caesium–thallium alloys with thallium concentrations of 50 to 85 at. % have been measured by means of neutron diffraction. They exhibit a prepeak which shifts to smaller wave vectors with increasing thallium content. This result is explained using a model in which neutral units CsmTln are dissolved in an excess of liquid thallium.

Country

Netherlands

Related Organizations

University of Groningen
Netherlands
Delft University of Technology
Netherlands

Keywords

K8IN11, POLYANIONS, BAND-STRUCTURE, CRYSTAL-STRUCTURE, CLUSTER

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