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Kinetics in dynamically disordered systems: Time scale dependence of reaction patterns in condensed media

Authors: Andrzej Plonka; Adam Paszkiewicz;

Kinetics in dynamically disordered systems: Time scale dependence of reaction patterns in condensed media

Abstract

The dependence of the patterns of reactions in condensed media on the time scale is rationalized in terms of the renewal theory with a fractal set of renewal moments which results from the use of Kohlrausch (1863) function to describe the structural relaxations in the systems. When the rates of relaxations exceed markedly those of reactions the classical patterns of reaction kinetics are shown to be valid for disordered systems. The dispersive nature of kinetics becomes evident when the rates of reactions approach those of structural relaxations and in the limit, corresponding to suppressed internal rearrangements, the reaction patterns are shown to be those following from reaction modeling in statically disordered systems.

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Powered by OpenAIRE graph
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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
39
Average
Top 10%
Top 10%
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