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Long-range, nonadiabatic effects in statistical adiabatic channel models: Dynamic orientation of diatomic fragments formed in the decomposition of long-lived triatomic complexes

Authors: E. I. Dashevskaya; E. E. Nikitin; J. Troe;

Long-range, nonadiabatic effects in statistical adiabatic channel models: Dynamic orientation of diatomic fragments formed in the decomposition of long-lived triatomic complexes

Abstract

Using the example of the decomposition of a long-lived triatomic complex into an atom and a diatom, it is shown that nonadiabatic interactions between adiabatic channel states at large interfragment distances strongly reduce the dynamic rotational orientation of the diatom. The degree of orientation is expressed in terms of a number of open adiabatic channels and ‘‘slipping factors.’’ These factors are estimated for an anisotropic potential following an inverse power law.

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Powered by OpenAIRE graph
Found an issue? Give us feedback
selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
19
Average
Top 10%
Top 10%
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