5  D  3–5D4 cross relaxation in Tb3+ pairs in CsCdBr3 crystals

P. A. M. Berdowski; M. J. J. Lammers; G. Blasse

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The Journal of Chemi...arrow_drop_down

The Journal of Chemical Physics

Article . 1985 . Peer-reviewed

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https://dx.doi.org/10.1063/1.4...

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5 D 3–5D4 cross relaxation in Tb3+ pairs in CsCdBr3 crystals

descriptionPublicationkeyboard_double_arrow_right Article 15 Jul 1985 English Publisher:AIP PublishingJournal:The Journal of Chemical Physics, volume 83, pages 476-479 (issn: 0021-9606, eissn: 1089-7690,

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Authors: P. A. M. Berdowski; M. J. J. Lammers; G. Blasse;

doi: 10.1063/1.449562

5 D 3–5D4 cross relaxation in Tb3+ pairs in CsCdBr3 crystals

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Abstract

The 5D3–5D4 cross relaxation process of Tb3+ in CsCdBr3 has been evaluated by analysis of the decay curves of the 5D3 and 5D4 emission. The temperature dependence of the cross relaxation rate can be explained assuming phonon-assisted processes. The results show that the larger amount of Tb3+ ions is incorporated in pairs into the CsCdBr3 lattice.

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