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Local modes and cross-correlation functions

Authors: J. T. Muckerman; D. W. Noid; M.S. Child;

Local modes and cross-correlation functions

Abstract

It is shown how the use of cross-correlation functions and their Fourier transforms provides a convenient probe of the division of the classical phase space for stretching vibrations of H2O into local, normal, and stochastic fractions. Resulting classical estimates for the numbers of total and local states, N(E) and Nl(E), respectively, as functions of energy are in excellent agreement with previous quantal and semiclassical results. The classical estimate of the number of stochastic states Ns(E) as a function of energy is a new result. The present method is readily generalizable to polyatomic molecules with many vibrational degrees of freedom.

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Powered by OpenAIRE graph
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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
20
Average
Top 10%
Top 10%
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