Intersystem crossing and predissociation of haloaromatics

descriptionPublicationkeyboard_double_arrow_right Article 01 Aug 1982 English Publisher:AIP PublishingJournal:The Journal of Chemical Physics, volume 77, pages 1,214-1,224 (issn: 0021-9606, eissn: 1089-7690,

Copyright policy )

Authors: D. Huppert; S. D. Rand; A. H. Reynolds; P. M. Rentzepis;

doi: 10.1063/1.443989

Intersystem crossing and predissociation of haloaromatics

- Summary
- Metrics

Abstract

The mechanism for the dissociation of several haloaromatic molecules has been investigated by means of absorption and emission picosecond spectroscopy. It is found that the rates of intersystem crossing and dissociation increase from chloro to bromo to iodo substituents. It is observed that the position of the halo substituent and temperature influence these rates. A model for the dissociation mechanism is proposed which is consistent with the absorption and emission data presented.

Impact byBIP!

	selected citations These citations are derived from selected sources. This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).	29
	popularity This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.	Average
	influence This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).	Top 10%
	impulse This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.	Average