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Frequency-dependent rate coefficient in diffusion-controlled reactions

Authors: B. U. Felderhof;

Frequency-dependent rate coefficient in diffusion-controlled reactions

Abstract

Diffusion-controlled reactions between particles and a nondilute system of sinks are studied. It is shown that in time-dependent situations it is necessary to take account of retardation effects in the building-up of correlations between competing sinks. The retardation leads to a frequency dependence of the rate coefficient. We derive corrections to the dilute limit value of the rate coefficient in the low concentration, low frequency regime. As an application we consider the effect on the time dependence of a quenching process.

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Powered by OpenAIRE graph
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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
21
Average
Top 10%
Average
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