We have performed experiments on the β‐decay of several Sn nuclides near 132Sn. The multiplet structure of 132,130Sb was studied and an extensive level scheme was constructed for the decay of the 7‐isomer in 130Sn. These investigations were extended to 131,129,127Sb where the properties of the more complex multiplets were determined. Extensive high‐spin level schemes were constructed for the decay of 131,129Sn and a 19/2‐, β‐decaying isomer was placed in the 129Sb level scheme. A partial level is presented for the decay of the 19/2‐ isomer into levels of 129Te.