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Colloidal rotation near the colloidal glass transition

Authors: Kim, Minsu; Anthony, Stephen M.; Bae, Sung Chul; Granick, Steve;

Colloidal rotation near the colloidal glass transition

Abstract

We compare, using single-particle optical imaging, trajectories of rotation and translation for micron-sized spheres in index-matched colloidal suspensions near their glass transition. Rotational trajectories, while they show intermittent caged behavior associated with supercooled and glassy behavior, explore a sufficiently wider phase space such that in the averaged mean-square angular displacement there appears no plateau regime, but instead sub-Fickian angular diffusion that follows an apparent power law in time. We infer translation and rotation time constants, the former being the time to diffuse a particle diameter and the latter being the time to rotate a full revolution. Correlation between time constants increases with increasing volume fraction, but unlike the case for molecular glasses, the rotation time constant slows more weakly than the translation time.

Country
Korea (Republic of)
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Powered by OpenAIRE graph
Found an issue? Give us feedback
selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
27
Top 10%
Top 10%
Average
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