The application of thermoelastic stress analysis in composite materials is particularly complicated because of the anisotropy of the material, that determines the thermoelastic constant to be dependent on the direction of the fibers. A further difficulty depends on the constructive stratification of the material, whose mechanical properties vary with the depth from the surface and this causes thermoelastic constants to be dependent on the frequency of the load applied. By using an analytical two layer model, it has been possible to interpret experimental data, thus proposing an explanation of the dependence on the frequency of the measured thermoelastic constants. This has shown that the practical use of the thermoelastic effect for quantitative stress analysis on composites needs constants calibrated at the correct frequency, also considering the thin layer of superficial resin present in every composite material.