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Co2+-Co2+ interaction in CoNb2O6

Authors: I. Yaeger; A. H. Morrish; B. M. Wanklyn;

Co2+-Co2+ interaction in CoNb2O6

Abstract

Neutron diffraction studies of CoNb2O6 powder at 2°K indicate an ordered antiferromagnetic structure of the Co2+ spins(1). The transition temperature has not been observed in the succeptibility and field induced magnetization measurements we took on flux grown single crystals of CoNb2O6 from 3.3°K to 300°K. The crystalographic space group of CoNb2O6 is Pbcn. Group theoretical analysis of Co2+‐Co2+ bilinear interactions within the Pbcn space group indicates that both symmetric and antisymmetric Co2+‐Co2+ interactions are allowed. We show that the salient features of our experimental results at temperatures below 50°K can be accounted for in terms of the interaction between Co2+ ions occupying the lowest lying Kramers’ doublet. The local principal axes of the g tensor for the Co2+ ground doublet at all sites are found practically to coincide with the orthorhombic crystal axes giving ga=4.1±0.2, gb=4.4±0.2 and gc=5.7±0.3. The Co2+−Co2+ antisymmetric interaction happens to be negligible as compared to the symmetric one. From the temperature dependence of the paramagnetic susceptibility it is found that the dominant Co2+−Co2+ interaction along the a and c directions is the intrasublattice antiferromagnetic interaction. A complete account of this work will be published elsewhere.

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
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