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Rheology of Carbon Black Suspensions: Effect of Carbon Black Structure

Authors: Yuji Aoki; Albert Co; Gary L. Leal; Ralph H. Colby; A. Jeffrey Giacomin;

Rheology of Carbon Black Suspensions: Effect of Carbon Black Structure

Abstract

Rheology of carbon black (CB) suspensions in an alkyd resin‐type varnish (Varnish‐2), a rosin‐modified phenol resin‐type varnish (Varnish‐1), and a polystyrene/di‐butyl phthalate (PS/DBP) solution was investigated to clarify the effects of CB morphology such as primary particle size and DBP absorption value (a measure of aggregate structure). It was found that the important parameters to characterize the CB aggregates are the effective volume fraction φeff of CB aggregates evaluated by plotting the relative viscosity ηr = η0/ηm (ηm: medium viscosity) on the universal ηr versus φ curve obtained for the hard‐core silica particles for CB/Varnish‐2 and CB/(PS/DBP) systems, and the critical gel concentration φcrit found for CB/Varnish‐1 systems. Because the φeff and φcrit values depended on DBP absorption value, irrespective of the primary particle size, and were found to be larger for the higher‐structure CB with higher DBP absorption value.

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citations
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
2
Average
Average
Average
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