
doi: 10.1063/1.2170074
pmid: 16497080
A correlation between the monomeric volume and the dynamic quantity EV*∕H*, used to provide a quantitative measure of the role of temperature and density on the dynamics, is demonstrated for a series of polymers and glass-forming liquids. We show that monomeric volume and local packing play a key role in controlling the value of this ratio and thus the dynamics associated with the glass temperature.
segmental relaxation, bonded polymer blends, supercooled liquids, forming liquids, x-ray-scattering, dielectric-relaxation, neutron-scattering, viscous slowing-down, glassforming liquids, disentangling density
segmental relaxation, bonded polymer blends, supercooled liquids, forming liquids, x-ray-scattering, dielectric-relaxation, neutron-scattering, viscous slowing-down, glassforming liquids, disentangling density
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