descriptionPublicationkeyboard_double_arrow_right Article 01 Nov 2004 English Publisher:AIP PublishingJournal:The Journal of Chemical Physics, volume 121, pages 8,179-8,182 (issn: 0021-9606, eissn: 1089-7690,

Authors: Carberry, D. M.; Williams, S. R.; Wang, G. M.; Sevick, E. M.; Evans, Denis J.;

doi: 10.1063/1.1802211

pmid: 15511135

handle: 1885/15803

The Kawasaki identity and the Fluctuation Theorem

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Abstract

In this paper we show that the Fluctuation Theorem of Evans and Searles [D. J. Evans, D. J. Searles, Phys. Rev. E 50, 1645 (1994)] implies that the Kawasaki function 〈exp(−Ωt)〉 is unity for all time t. We confirm this relationship using experimental data obtained using optical tweezers, and show that the Kawasaki function is a valuable diagnostic tool.

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University of Queensland
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Keywords

General Physics and Astronomy, Physical and Theoretical Chemistry

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