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The Swelling of Unfilled and Highly Filled Polymers

Authors: Kenneth W. Bills; F. S. Salcedo;

The Swelling of Unfilled and Highly Filled Polymers

Abstract

The swelling of elastomers in solvents is a useful method for determining the effective crosslinking of the polymeric structure. However, it is now shown that this method may be applied satisfactorily to highly filled polymers. A unique method has been devised for the accurate measurement of the swelling ratio of the gel phase of the filled polymers. The method is based on the observation that the binder-filler bond, for most filler particles, releases on swelling. The binder around the particle swells, leaving a hollow pocket which becomes filled with solvent. Corrections for this ``waste'' solvent lead to the equations from which the swelling of the polymer can be calculated. Experimental verification is given for several filled systems.

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citations
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
13
Average
Top 10%
Average
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