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Absolute Rates of Four-Atom Reactions

Authors: Wm. Altar; H. Eyring;

Absolute Rates of Four-Atom Reactions

Abstract

Equipotential surfaces such as one encounters in valence problems and particularly in the calculation of absolute rates, are discussed in a ``bond space'' instead of configuration space, with much simplification resulting both in the general aspects and in the practical handling of such problems. The exchange part, as well as the so-called coulombic part, of the bond energies is seen to obey a simple vector addition rule. A complete treatment of a four-atom reaction without symmetry (H2+ICl→HI+HCl) is carried out and results are compared with the existing experiments.

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
10
Average
Top 10%
Average
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