The Entropy of Polyatomic Molecules

descriptionPublicationkeyboard_double_arrow_right Article 01 Oct 1934 English Publisher:AIP PublishingJournal:The Journal of Chemical Physics, volume 2, pages 694-696 (issn: 0021-9606, eissn: 1089-7690,

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Authors: J. O. Halford;

doi: 10.1063/1.1749376

The Entropy of Polyatomic Molecules

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Abstract

A general expression for the entropy of the polyatomic molecule, rigid in the sense that only one form with a given set of moments of inertia is possible, is tested by comparison of calculated and experimental values. The results are satisfactory for molecules with as many as seven rotational degrees of freedom.

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University of Michigan–Flint
United States

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