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The Journal of Chemical Physics
Article . 2004 . Peer-reviewed
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Shear stress relaxation in liquids

Authors: Petravic, Janka;

Shear stress relaxation in liquids

Abstract

We show that at high densities, as the system size decreases, liquid becomes able to permanently sustain increasing internal shear stress after a constant deformation, although the other characteristic liquid properties, such as the pair distribution function and diffusion coefficient do not change under strain. The system size necessary for observation of this effect increases with the decrease in temperature, and it is stronger in pair potentials with steeper repulsive part. We relate this result to the size of the “cooperatively rearranging regions” of the Adam–Gibbs theory of glass transition.

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Croatia, Australia
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Keywords

Mathematical models, Shear stress, Viscosity, Keywords: Crystallization, Elastic moduli, Relaxation time, Configurational entropy, Deformation energy, Deformation, Materials science, shear stress, Diffusion, relaxation, Stress relaxation, Supercooled liquids, liquid, shear stress ; relaxation ; liquid ; glass, Glass transition, Supercooling, glass

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    popularity
    This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
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    influence
    This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
11
Average
Average
Average
Green
bronze