
We show that at high densities, as the system size decreases, liquid becomes able to permanently sustain increasing internal shear stress after a constant deformation, although the other characteristic liquid properties, such as the pair distribution function and diffusion coefficient do not change under strain. The system size necessary for observation of this effect increases with the decrease in temperature, and it is stronger in pair potentials with steeper repulsive part. We relate this result to the size of the “cooperatively rearranging regions” of the Adam–Gibbs theory of glass transition.
Mathematical models, Shear stress, Viscosity, Keywords: Crystallization, Elastic moduli, Relaxation time, Configurational entropy, Deformation energy, Deformation, Materials science, shear stress, Diffusion, relaxation, Stress relaxation, Supercooled liquids, liquid, shear stress ; relaxation ; liquid ; glass, Glass transition, Supercooling, glass
Mathematical models, Shear stress, Viscosity, Keywords: Crystallization, Elastic moduli, Relaxation time, Configurational entropy, Deformation energy, Deformation, Materials science, shear stress, Diffusion, relaxation, Stress relaxation, Supercooled liquids, liquid, shear stress ; relaxation ; liquid ; glass, Glass transition, Supercooling, glass
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