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Viscosity of Polymer Solutions

Authors: James M. Peterson; M. Fixman;

Viscosity of Polymer Solutions

Abstract

In the expression for the viscosity of polymer solutions η=η0+[η]C+K[η]2C2+···, the Huggins constant K is calculated for hard spheres and for interpenetrable spheres of uniform segment density. For hard spheres K = 0.6909, and for soft spheres where K is larger, the dependence of K on the segment—segment interaction constant is given. Difficulties in the basic theory caused by the long range of hydrodynamic perturbations are resolved. The theory is approximate, in that the velocity field arising from Sphere 1 is assumed to vary slowly in the vicinity of 2, but within this approximation all orders of ``reflections'' are correctly summed.

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
117
Top 10%
Top 1%
Average
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