
doi: 10.1063/1.1734055
In the expression for the viscosity of polymer solutions η=η0+[η]C+K[η]2C2+···, the Huggins constant K is calculated for hard spheres and for interpenetrable spheres of uniform segment density. For hard spheres K = 0.6909, and for soft spheres where K is larger, the dependence of K on the segment—segment interaction constant is given. Difficulties in the basic theory caused by the long range of hydrodynamic perturbations are resolved. The theory is approximate, in that the velocity field arising from Sphere 1 is assumed to vary slowly in the vicinity of 2, but within this approximation all orders of ``reflections'' are correctly summed.
| selected citations These citations are derived from selected sources. This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically). | 117 | |
| popularity This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network. | Top 10% | |
| influence This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically). | Top 1% | |
| impulse This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network. | Average |
