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Energies of, and Transition Intensities Associated with, the Rotational Levels of Nearly Degenerate A1A2 Pairs of Vibronic States in Molecules of Symmetry C3v

Authors: Jon T. Hougen;

Energies of, and Transition Intensities Associated with, the Rotational Levels of Nearly Degenerate A1A2 Pairs of Vibronic States in Molecules of Symmetry C3v

Abstract

Expressions for the energies of the rotational levels associated with a nearly degenerate A1A2 pair of vibronic states in a molecule of symmetry C3v are presented. These expressions take into consideration Coriolis interaction between the levels associated with the A1 vibronic state and the levels associated with the A2 vibronic state. Expressions for the intensities of rotational lines in transitions involving such a nearly degenerate A1A2 pair of vibronic states are also presented. In certain cases transitions involving a (accidentally) degenerate A1A2 pair of vibronic states will have the same appearance as transitions involving a (necessarily) degenerate E vibronic state. A loose analogy between the problem discussed in this paper and the problem of spin uncoupling in a 2Π state of a diatomic molecule is pointed out.

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citations
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
34
Average
Top 10%
Average
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