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Effect of Absorbed Water upon the Dielectric Properties of Certain Acrylic Ester Polymers

Authors: Donald J. Scheiber; Darwin J. Mead;

Effect of Absorbed Water upon the Dielectric Properties of Certain Acrylic Ester Polymers

Abstract

The effect of absorbed water upon the dielectric properties of polymethylmethacrylate, polyethylmethacrylate, and polyethylacrylate is experimentally investigated over a temperature range from 70°C to —195°C and at frequencies between 100 cps and 200 kc. It is found in each case that the absorbed water gives rise to a discernible loss index peak in the low-temperature region (0° to —100°C). The 2.1% water absorbed in a specimen of polyethylacrylate acts as a plasticizer, apparently lowering the glass transition by 5C°. The facts that the apparent activation energy and the temperature location of the water induced peak changes with variations in the polymeric structure indicate that the induced loss peak is not to be identified with the loss peak found in ice, and furthermore suggests that the dielectric method can be employed to learn more about the water—polymer complex which is formed when water is absorbed into a polymer.

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
4
Average
Top 10%
Average
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