Powered by OpenAIRE graph
Found an issue? Give us feedback
addClaim

Intrinsic mobility of molecular glasses

Authors: Gyan P. Johari;

Intrinsic mobility of molecular glasses

Abstract

The dielectric relaxation study of glass-forming liquids show the presence of two relaxation regions at temperatures above TQ. The low frequency relaxation is attributed to the cooperative rearrangement of molecules. The high frequency relaxation, which continues to exist in the glassy state, is suggested to arise from the hindered rearrangement of the molecules encaged by large regions which have been made relatively immobile by the stringent requirement of a cooperative motion. The hindered reorientation of dipoles in liquids at low viscosity has about the same Arrhenius energy as the β process seen in glasses. The results emphasize the role of intermolecular potential barriers in producing relaxation characteristics which have been generally accepted to arise from intramolecular rearrangement.

Related Organizations
  • BIP!
    Impact byBIP!
    selected citations
    These citations are derived from selected sources.
    This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    340
    popularity
    This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
    Top 10%
    influence
    This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    Top 1%
    impulse
    This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
    Top 10%
Powered by OpenAIRE graph
Found an issue? Give us feedback
selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
340
Top 10%
Top 1%
Top 10%
Upload OA version
Are you the author of this publication? Upload your Open Access version to Zenodo!
It’s fast and easy, just two clicks!