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Statistical Theory of Bimolecular Exchange Reactions: Angular Distribution

Authors: R. A. White; J. C. Light;

Statistical Theory of Bimolecular Exchange Reactions: Angular Distribution

Abstract

The statistical theory of chemical reactions is extended to describe the angular distributions of the products. The random phase approximation is used and the coefficients of the spherical harmonics are computed statistically. The distributions, symmetric about 90° in the center-of-mass frame, are then transformed to the lab frame. Application was made to the Rb+CsCl→RbCl+Cs reaction. The agreement with experiment is only moderate, implying that the statistical theory predicts too little internal excitation of the products in spite of the fact that experimentally the formation of a complex seems likely.

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Powered by OpenAIRE graph
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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
37
Average
Top 10%
Top 10%
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