Mössbauer Study of Soluble Prussian Blue, Insoluble Prussian Blue, and Turnbull's Blue

descriptionPublicationkeyboard_double_arrow_right Article 15 Apr 1968 English Publisher:AIP PublishingJournal:The Journal of Chemical Physics, volume 48, pages 3,597-3,599 (issn: 0021-9606, eissn: 1089-7690,

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Authors: A. Ito; M. Suenaga; K. Ôno;

doi: 10.1063/1.1669656

Mössbauer Study of Soluble Prussian Blue, Insoluble Prussian Blue, and Turnbull's Blue

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Abstract

The electronic structures of soluble Prussian blue, insoluble Prussian blue, and Turnbull's blue were investigated by the Mössbauer effect of 57Fe. The results below their Curie temperatures of 5.5° ± 0.5°K show that all of them are ferric ferrocyanide: one kind of irons is Fe3 + with high spin and the other is Fe(II) with low spin. It is concluded that Prussian blue and Turnbull's blue have the same electronic structure. The results of a paramagnetic resonance absorption observed at room temperature also support the conclusions obtained by the Mössbauer study.

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