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Hal
Article . 1992
Data sources: Hal
Journal de Physique II
Article . 1992 . Peer-reviewed
Data sources: Crossref
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Rheology of mesogels

Authors: Uwe Zölzer; Hans-Friedrich Eicke;

Rheology of mesogels

Abstract

The effect of triblock copolymers (polyoxyethylene-polyisoprene-polyoxyethylene) on the interaction potential and network formation of nanodroplets in w/o microemulsions, i.e. on the formation of “mesogels”, has been studied by flow- and oscillatory shear measurements. Frequency dependent storage and loss moduli, the zero shear viscosity and the terminal relaxation times were determined which agree well with predictions from scaling laws for homopolymer solutions ; lifetimes of network crosslinks were determined from the transition of Newtonian to viscoelastic behaviour that agree with the characteristic time constant which correspond to the crossover from restricted to free diffusion of the copolymer. The activation energy of viscous flow at large copolymer concentrations shows a logarithmic concentration dependence from which a power law dependence of the viscosity against copolymer concentration can be derived if an Arrhenius relation for the temperature dependent viscosity is assumed.

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[PHYS.HIST] Physics [physics]/Physics archives

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citations
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
15
Average
Top 10%
Average
Green