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International Journal of Energy Research
Article . 1979 . Peer-reviewed
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Faraday Discussions of the Chemical Society
Article . 1980 . Peer-reviewed
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Synthetic chloroplasts

Authors: Calvin, Melvin;

Synthetic chloroplasts

Abstract

The principal function of the chloroplast is to capture solar quanta and to store them in some stable form. We are in the process of trying to construct a totally synthetic system that would simulate some of the reactions of the two photosystems which occur in natural chloroplasts. Toward this end, we have demonstrated a number of the reactions required in separated systems. We have shown that it is possible to transfer electrons across an insulating membrane barrier with a surfactant photosensitizer. Others have shown, and we have confirmed, that it is possible to collect the two electrons necessary for the generation of molecular hydrogen on a heterogeneous catalyst suspended in water and similarly to collect the four holes on another heterogeneous catalyst suspended in water for the generation of molecular oxygen. A synthesis of some of these molecular catalysts for both these purposes is underway, with some partial success. When these partial reactions are assembled in a system, the resulting synthetic chloroplasts will not resemble the natural entity in detailed construction as they will contain no protein.

Keywords

Biomimetic Processes, Chloroplasts, Porphyrins, & Thermochemical Conversion-- (1980-), Cryogenic Fluids, Carboxylic Acids, Electron Transfer, Research Programs, Synthesis, Heterocyclic Compounds, Cell Constituents, Photosynthesis, Transition Elements 140505* -- Solar Energy Conversion-- Photochemical, Photochemical Reactions, Manganese, Fluids, Membranes, Catalysts, Organic Compounds, Photobiological, Chemical Reactions, 14 Solar Energy, Elements, General and Miscellaneous, Oxygen, Nonmetals, Organic Acids, Organic Nitrogen Compounds, Heterocyclic Acids, Metals, Hydrogen

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    This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    45
    popularity
    This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
    Average
    influence
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    impulse
    This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
    Top 10%
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citations
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
45
Average
Top 10%
Top 10%
Green
gold