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Physical Chemistry Chemical Physics
Article . 2025 . Peer-reviewed
License: CC BY NC
Data sources: Crossref
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DIGITAL.CSIC
Article . 2025 . Peer-reviewed
Data sources: DIGITAL.CSIC
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Boron beats nitrogen: strained boron–boron bonds as (molecular) proton sponges

Authors: Ibon Alkorta; José Elguero; M. Merced Montero-Campillo; Otilia Mó; Manuel Yáñez;

Boron beats nitrogen: strained boron–boron bonds as (molecular) proton sponges

Abstract

The basicity and the hydrogen bond (HB) acceptor capability of diborane derivatives of dipyrazole 1 with a B–B bond have been studied theoretically using M06-2x and CCSD(T) methods. The proton affinities of 1b reach 1096 kJ mol−1.

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    popularity
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    influence
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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
0
Average
Average
Average
Green
hybrid