Organocatalytic atroposelective synthesis of naphthoquinone thioglycosides from aryl-naphthoquinones and thiosugars

descriptionPublicationkeyboard_double_arrow_right Article 01 Jan 2023 English Publisher:Royal Society of Chemistry (RSC)Journal:Chemical Communications, volume 59, pages 7,279-7,282 (issn: 1359-7345, eissn: 1364-548X,

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Authors: Yuling Wu; Wu-Jingyun Zhou; Laiping Yao; Yadi Niu; Hongli Zhao; Cheng Peng; Bo Han; +2 Authors

doi: 10.1039/d3cc01705b

pmid: 37227142

Organocatalytic atroposelective synthesis of naphthoquinone thioglycosides from aryl-naphthoquinones and thiosugars

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Abstract

A stereoselective organocatalytic strategy was developed to synthesize the axially chiral naphthoquinone thioglycosides from aryl-naphthoquinones and thiosugars. The reaction pathway involves atroposelective addition and stereoretentive oxidation.

Related Organizations

Chengdu University of Traditional Chinese Medicine
China (People's Republic of)

Keywords

Thioglycosides, Thiosugars, Naphthoquinones

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