Electrocatalytic alcohol oxidation by a molecular iron complex

descriptionPublicationkeyboard_double_arrow_right Article 01 Jan 2022 English Publisher:Royal Society of Chemistry (RSC)Journal:Faraday Discussions, volume 234, pages 42-57 (issn: 1359-6640, eissn: 1364-5498,

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Authors: Himangshu Kuiry; Debasree Das; Soumadip Das; Soham Chakraborty; Bittu Chandra; Sayam Sen Gupta;

doi: 10.1039/d1fd00074h

pmid: 35174376

Electrocatalytic alcohol oxidation by a molecular iron complex

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Abstract

An efficient electrochemical method for the selective oxidation of alcohols to their corresponding aldehydes/ketones using a biomimetic iron complex, [(bTAML)FeIII–OH2]−, as the redox mediator in an undivided electrochemical cell with inexpensive carbon and nickel electrodes using water as an oxygen source is reported.

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Keywords

Oxygen, Alcohols, Iron, Electrons, Oxidation-Reduction

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