Proton in the ring: spectroscopy and dynamics of proton bonding in macrocycle cavities

descriptionPublicationkeyboard_double_arrow_right Article 01 Jan 2021 Netherlands English Publisher:Royal Society of Chemistry (RSC)Journal:Physical Chemistry Chemical Physics, volume 23, pages 21,532-21,543 (issn: 1463-9076, eissn: 1463-9084,

Copyright policy )Funded by:EC | CALIPSOplus, FCT | D4

Authors: Francisco Gámez; Juan R. Avilés-Moreno; Giel Berden; Jos Oomens; Bruno Martínez-Haya;

doi: 10.1039/d1cp03033g

pmid: 34549205

handle: https://repository.ubn.ru.nl/handle/2066/238814

Proton in the ring: spectroscopy and dynamics of proton bonding in macrocycle cavities

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Abstract

Protons confined in the ring cavities of crown ethers form dynamic proton bonds that migrate to varying pairs of coordinating atoms, at a rate depending on electronegativity and on the flexibility of the macrocycle backbone.

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Netherlands

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Keywords

FELIX Molecular Structure and Dynamics

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