An umpolung strategy for rapid access to thermally activated delayed fluorescence (TADF) materials based on phenazine

descriptionPublicationkeyboard_double_arrow_right Article 01 Jan 2022 English Publisher:Royal Society of Chemistry (RSC)Journal:Chemical Communications, volume 58, pages 1,581-1,584 (issn: 1359-7345, eissn: 1364-548X,

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Authors: Huaxing Zhang; Qiang Guo; Hu Cheng; Chunhao Ran; Di Wu; Jingbo Lan;

doi: 10.1039/d1cc06705b

pmid: 35018392

An umpolung strategy for rapid access to thermally activated delayed fluorescence (TADF) materials based on phenazine

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Abstract

Ag(I)-promoted regioselective intramolecular radical nucleophilic addition/rearrangement of 2-aryl diazaboroles has been accomplished to construct phenazine structures, which is an umpolung strategy based on the classical electrophilic mechanism.

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Sichuan University
China (People's Republic of)
Chengdu University of Information Technology
China (People's Republic of)

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