Halogen bonding organocatalysis enhanced through intramolecular hydrogen bonds

descriptionPublicationkeyboard_double_arrow_right Article 01 Jan 2022 English Publisher:Royal Society of Chemistry (RSC)Journal:Chemical Communications, volume 58, pages 1,378-1,381 (issn: 1359-7345, eissn: 1364-548X,

Copyright policy )Funded by:NIH | Biomolecular Structure an..., NSF | MRI: Acquisition of a Sma..., NSF | CAREER: Fundamental Studi...

Authors: Asia Marie S. Riel; Daniel A. Decato; Jiyu Sun; Orion B. Berryman;

doi: 10.1039/d1cc05475a

pmid: 34989732

pmc: PMC8919959

Halogen bonding organocatalysis enhanced through intramolecular hydrogen bonds

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Abstract

The Hydrogen Bond enhanced Halogen Bond (HBeXB) represents a new method to preorganize molecular structure and enhance catalytic activity. Here we show that a HBeXB organocatalyst exhibits enhanced activity over a strictly halogen bonding catalyst.

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