Anion–anion and anion–neutral triel bonds

descriptionPublicationkeyboard_double_arrow_right Article 01 Jan 2021 United States English Publisher:Royal Society of Chemistry (RSC)Journal:Physical Chemistry Chemical Physics, volume 23, pages 4,818-4,828 (issn: 1463-9076, eissn: 1463-9084,

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Authors: Rafał Wysokiński; Mariusz Michalczyk; Wiktor Zierkiewicz; Steve Scheiner;

doi: 10.1039/d0cp06547a

pmid: 33605957

Anion–anion and anion–neutral triel bonds

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Abstract

TrCl4−(Tr = Al, Ga, In, Tl) anion is able to engage in complexes with two Lewis bases: neutral NH3or the CN−anion through a triel bond. Complexation leads to two types of geometries: axial and equatorial.

Country

United States

Related Organizations

Utah State University
United States
Wrocław University of Science and Technology
Poland

Keywords

triel bonds, Chemistry, 541

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