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Chemical Science
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Chemical Science
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The hydrogen atom transfer reactivity of sulfinic acids

descriptionPublicationkeyboard_double_arrow_right Article 01 Jan 2018 English Publisher:Royal Society of Chemistry (RSC)Journal:Chemical Science, volume 9, pages 7,218-7,229 (issn: 2041-6520, eissn: 2041-6539, Copyright policy )Funded by:NSERC | unidentified
Authors: Markus Griesser; Jean-Philippe R. Chauvin; Derek A. Pratt;

doi: 10.1039/c8sc02400f

pmid: 30288241

pmc: PMC6148200

The hydrogen atom transfer reactivity of sulfinic acids

Abstract

Sulfinic acids are characterized to be very good H-atom donors to each of alkyl and alkoxyl radicals. In order to participate in useful radical chain reactions, the sulfonyl radicals must undergo fast propagating reactions to avoid autoxidation, which is surprisingly rate-limited by the reaction of sulfonyl radicals with oxygen.

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
32
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Top 10%
Top 10%
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