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Chemical Communications
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Chemical Communications
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Chemical Communications
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https://dx.doi.org/10.1039/c8c...
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Unravelling nucleophilic aromatic substitution pathways with bimetallic nucleophiles

descriptionPublicationkeyboard_double_arrow_right Article 01 Jan 2019 United Kingdom English Publisher:Royal Society of Chemistry (RSC)Journal:Chemical Communications, volume 55, pages 1,805-1,808 (issn: 1359-7345, eissn: 1364-548X, Copyright policy )Funded by:EC | FluoroFix
Authors: Martí Garçon; Clare Bakewell; Andrew J. P. White; Mark R. Crimmin;

doi: 10.1039/c8cc09701a

pmid: 30667423

handle: 10044/1/66723

Unravelling nucleophilic aromatic substitution pathways with bimetallic nucleophiles

Abstract

Reaction of nucleophiles containing polar (Fe–Mg) and apolar (Mg–Mg) bonds with 2-(pentafluorophenyl)pyridine are calculated to proceed by stepwise and concerted SNAr pathways respectively.

Country
United Kingdom
Related Organizations
Keywords

Science & Technology, Multidisciplinary, Organic Chemistry, MG-MG, 500, METAL-CARBONYL CHEMISTRY, FLUOROARENES, 540, ANIONS, PERFLUOROCARBONS, Chemistry, INTERMEDIATE, BOND ACTIVATION, OXIDATIVE ADDITION, Physical Sciences, C-F, 03 Chemical Sciences

  • BIP!
    Impact byBIP!
    selected citations
    These citations are derived from selected sources.
    This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    		 14
    popularity
    This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
    		 Top 10%
    influence
    This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    		 Average
    impulse
    This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
    		 Top 10%
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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
14
Top 10%
Average
Top 10%
Green
bronze
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