Enantioselective incorporation of dicarboxylate guests by octacalcium phosphate

descriptionPublicationkeyboard_double_arrow_right Article 01 Jan 2017 English Publisher:Royal Society of Chemistry (RSC)Journal:Chemical Communications, volume 53, pages 6,524-6,527 (issn: 1359-7345, eissn: 1364-548X,

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Authors: Taishi Yokoi; Shingo Machida; Yoshiyuki Sugahara; Masami Hashimoto; Satoshi Kitaoka;

doi: 10.1039/c7cc01169e

pmid: 28573292

Enantioselective incorporation of dicarboxylate guests by octacalcium phosphate

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Abstract

We have investigated the effects of guest molecule chirality on incorporation into octacalcium phosphate (OCP). OCP incorporates (S)-(−)-methylsuccinic acid (MeSuc), while no significant amount of (R)-(+)-MeSuc is incorporated. This enantioselectivity clearly indicates that OCP recognizes the steric structures of guest molecules.

Related Organizations

Japan Fine Ceramics Center
Japan
Institute for Materials Research, Tohoku University
Japan
Waseda University
Japan

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