Cooperative Lewis acidity in borane-substituted fluorophosphonium cations

descriptionPublicationkeyboard_double_arrow_right Article 01 Jan 2016 English Publisher:Royal Society of Chemistry (RSC)Journal:Chemical Communications, volume 52, pages 6,387-6,390 (issn: 1359-7345, eissn: 1364-548X,

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Authors: Juri, Möbus; Thorsten, Vom Stein; Douglas W, Stephan;

doi: 10.1039/c6cc02607a

pmid: 27096885

Cooperative Lewis acidity in borane-substituted fluorophosphonium cations

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Abstract

Fluorophosphonium salts C6X4(BR2)Ph2PF[B(C6F5)4] (X = H, F; R = Cy, Mes) exhibit enhanced Lewis acid catalytic reactivity as a results of the proximity of the fluorophosphonium and borane moieties.

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