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Deciphering the roles of multiple additives in organocatalyzed Michael additions

descriptionPublicationkeyboard_double_arrow_right Article , Other literature type 01 Jan 2016 United Kingdom, Italy English Publisher:Royal Society of Chemistry (RSC)Journal:Chemical Communications, volume 52, pages 6,821-6,824 (issn: 1359-7345, eissn: 1364-548X, Copyright policy )Funded by:EC | MOMES
Authors: Günler, Z. Inci; Companyó, Xavier; Alfonso, Ignacio; Burés, Jordi; Jimeno, Ciril; Pericàs, Miquel A.;

doi: 10.1039/c6cc01026a

pmid: 27128165

handle: 11577/3268602 , 10044/1/32295

Deciphering the roles of multiple additives in organocatalyzed Michael additions

Abstract

The synergistic effects of multiple additives (water and acetic acid) on the asymmetric Michael addition of acetone to nitrostyrene catalyzed by primary amine-thioureas (PAT) were precisely determined.

Countries
United Kingdom, Italy
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Keywords

Science & Technology, Multidisciplinary, 1,3-DICARBONYL COMPOUNDS, CONTINUOUS-FLOW, ASYMMETRIC ALDOL REACTION, Organic Chemistry, AMINE-THIOUREA CATALYST, MECHANISTIC RATIONALIZATION, Chemistry, DIRECT CONJUGATE ADDITION, Physical Sciences, BIFUNCTIONAL ORGANOCATALYSTS, WATER, NITROALKENES, ALPHA-AMINATION, 03 Chemical Sciences, Catalysis; Electronic, Optical and Magnetic Materials; Ceramics and Composites; Chemistry (all); Surfaces, Coatings and Films; 2506; Materials Chemistry2506 Metals and Alloys

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    This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    		 14
    popularity
    This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
    		 Average
    influence
    This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
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    impulse
    This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
14
Average
Average
Top 10%
Green
hybrid
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