Gearing motion in cogwheel pairs of molecular rotors: weak-coupling limit

descriptionPublicationkeyboard_double_arrow_right Article 01 Jan 2015 Czech Republic English Publisher:Royal Society of Chemistry (RSC)Journal:CrystEngComm, volume 17, pages 7,829-7,834 (eissn: 1466-8033,

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Authors: Kaleta, J. (Jiří); Michl, J. (Josef); Méziere, C.; Simonov, S.; Zorina, L.; Wzietek, P.; Rodríguez-Fortea, A.; +2 Authors

doi: 10.1039/c5ce01372k

handle: 11104/0252168

Gearing motion in cogwheel pairs of molecular rotors: weak-coupling limit

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Abstract

Investigation of the rotor dynamics by X-ray diffraction, spin–lattice relaxation, and DFT modelling of the two rotational barriers in arrays of rod-like molecules with 1,3-bis(ethynyl)bicyclo[1.1.1]pentane rotators conclude to gearing motion between two rotors in a pair.

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Czech Republic

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University of Colorado System
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Spanish National Research Council
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Institute of Organic Chemistry and Biochemistry
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Keywords

correlated motion, dynamics, organic frameworks

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