Nucleophilic displacement of ammonia from ammonia borane for the preparation of alkylamine-, pyridine- and phosphine-boranes

descriptionPublicationkeyboard_double_arrow_right Article 01 Jan 2014 English Publisher:Royal Society of Chemistry (RSC)Journal:RSC Advances, volume 4, page 26,207 (eissn: 2046-2069,

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Authors: P. Veeraraghavan Ramachandran; Ameya S. Kulkarni;

doi: 10.1039/c4ra03397c

Nucleophilic displacement of ammonia from ammonia borane for the preparation of alkylamine-, pyridine- and phosphine-boranes

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Abstract

A near quantitative and safe preparation of a series of aliphatic amine- and phosphine-boranes from ammonia borane (AB) in refluxing THF has been achieved by exploiting the volatility of ammonia. A one-pot preparation of lithium aminoborohydrides from AB has also been described.

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Purdue University West Lafayette
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Purdue University System
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